I made this wallpaper in Photoshop CS4. My favourite stock photo site is http://www.sxc.hu which is where I got the skull (picture by dogmadic) and the eyeballs. Both pictures have been heavily modified with the special effects all being a combination of patterns, filters and renders. Of course there is a lot more to the wallpaper but that's the "meat" of what I did to get these effects.
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The main focus of Very Simple Designs is to provide digital resources that can be used for print and web design. While we fill the site to the brim with our professionally created vector stock, patterns and textures as well as brushes for Photoshop and Paintshop Pro, we offer everything free for personal use.